Material Safety Data Sheet according to directive (UE) 453/2010 Page 1 of 6
R600a < 1000 mL
Code: TR600
1.IDENTIFICATION OF PREPARATION AND SOCIETY
1.1 Description trade: R600a < 1000 mL
Code: TR600
1.2 Uses planned: Industry: Refrigerant and conditioning
Type of use: Refrigerant
Application: Professional
1.3 Society: MARIEL S.R.L.
Via Olubi, 5 - 28013 - GATTICO (NO) - Italy
Phone: +39 0322 838319
Fax: +39 0322 838813
e-mail:
[email protected]
1.4 Emergency number: + 39 0322 838319 - 8.30-12.30 / 13.30-17.30
Medical Center (Italy) ( 24/24 h service)
Pavia +39 0382 24444 (CAV IRCCS Fondazione Maugeri – Pavia - Italy)
Milano +39 02 66101029 (CAV Ospedale Niguarda Ca’ Granda – Milano - Italy)
Bergamo +39 800 883300 (CAV Ospedali Riuniti – Bergamo - Italy)
Firenze +39 055 7947819 (CAV Ospedale Careggi – Firenze - Italy)
Roma +39 06 3054343 (CAV Policlinico Gemelli – Roma - Italy)
Roma +39 06 49978000 (CAV Policlinico Umberto I – Roma - Italy)
Napoli +39 081 7472870 (CAV Ospedale Cardarelli – Napoli - Italy)
2. IDENTIFICATION OF DANGERS
Reg. CE 1272/2008:
H220 – Extremely flammable.
H280 – Pressurised container; the container may burst with high temperature.
P210 – Keep away from sources of ignition - No smoking.
P377 - Take precautionary measures against static discharges.
P381 – Eliminare ogni fonte di accensione se non c'è pericolo.
P403 – Keep container in a well-ventilated place;
2.1 Hazards information:
Liquefied gas.
Extremely flammable.
2.2 Classification CE :
F+;R12
Material Safety Data Sheet according to directive (UE) 453/2010 Page 2 of 6
R600a < 1000 mL
Code: TR600
3. COMPOSITION AND INFORMATION ON INGREDIENTS
3.1 Description:
Name of the chemical substance: Isobutane.
100% Isobutane EC 200-857-2
CAS 75-28-5
For more information on hazardous components, see sections 8, 11, 12 and 16.
4. FIRST AID MEASURES
If inhaled, remove to fresh air. If breathing is difficult, give oxygen. If not breathing, give artificial respiration. Get medical attention.
Notes to physician: Do not give adrenaline or similar drugs.
4.1 Inhalation:
In high concentrations may cause asphyxiation. Symptoms may include loss of mobility/consciousness. Victim may not be aware of asphyxiation. In low
concentrations may cause narcotic effects. Symptoms may include dizziness, headache, nausea and loss of co-ordination. Remove victim to
uncontaminated area wearing self contained breathing apparatus. Keep victim warm and rested. Call a doctor. Apply artificial respiration if breathing
stopped.
4.2 Skin Contact:
Dermal contact with rapidly evaporating liquid could result in freezing of the tissues or frostbite. In case of contact with liquid, warm frozen tissues with
water and get medical attention. Remove contaminated clothing and shoes. Wash clothing before reuse.
4.3 Eye Contact:
Immediately flush eyes with a large amount of water for at least 15 minutes. If symptoms exist and/or persist, get prompt medical attention.
4.4 Ingestion:
As this product is a gas, refer to the inhalation section. Do not induce vomiting unless directed to do so by medical personnel. Never give anything by
mouth to an unconscious person. Get medical attention.
5. FIRE FIGHTING MEASURES
5.1 Extinguishing Agents:
Extremely flammable. All known extinguishants can be used.
5.2 Unusual Hazards:
Exposure to fire may cause containers to rupture/explode.
5.3 Personal Protective Equipment:
Fire-fighters should wear self-contained positive pressure breathing apparatus (SCBA) and full turnout gear.
5.4 Hazardous thermal decomposition products Special exposure hazards:
Incomplete combustion may form carbon monoxide. Move away from the container and cool with water from a protected position.
Do not extinguish a leaking gas flame unless absolutely necessary. Spontaneous.
Material Safety Data Sheet according to directive (UE) 453/2010 Page 3 of 6
R600a < 1000 mL
Code: TR600
6. ACCIDENTAL SPILL OR LEAK RELEASE INFORMATION
6.1 Personal Protection:
Immediately contact emergency personnel. Keep unnecessary personnel away. Use suitable protective equipment (Section 8). Provide adequate
ventilation. In case of insufficient ventilation, wear suitable respiratory equipment.
6.2 Procedures:
Stop leak if without risk. Spillages may evaporate rapidly.
7. HANDLING AND STORAGE
7.1 FIRE AND EXPLOSIVE PROPERTIES:
Keep container below 50°C in a well ventilated plac e.
7.2 Storage Conditions:
Store in original container, protected from direct sunlight. Keep container tightly closed in a cool, well- ventilated place.
- Handling Procedures:
Segregate from oxidant gases and other oxidants in store.
Ensure equipment is adequately earthed. Suck back of water into the container must be prevented. Purge air from system before introducing gas. Do not
allow backfeed into the container. Use only properly specified equipment which is suitable for this product, its supply pressure and temperature. Contact
your gas supplier if in doubt. Keep away from ignition sources (including static discharges).
Refer to supplier's container handling instructions.
8. EXPOSURE CONTROLS AND PERSONAL PROTECTION
8.1 Exposure Limits (TLV) TLV-TWA TLV-STEL
AGCIH 2001 ppm mg/m3 ppm mg/m3
Isobutane 800 1900
TLV - Threshold Limit Value, TWA - Time Weighted Average, STEL - Short Term Exposure Limit.
8.2 Ventilation:
Provide adequate ventilation. Do not enter storage areas and confined spaces unless adequately ventilated.
Respiratory Protection:
In case of insufficient ventilation, wear suitable respiratory equipment. Recommended: supplied-air respirator.
- Eye Protection: Recommended: safety glasses with side shields, splash goggles. Possible: face shield.
- Hand Protection: Insulated gloves suitable for low temperatures. Recommended: butyl rubber
Material Safety Data Sheet according to directive (UE) 453/2010 Page 4 of 6
R600a < 1000 mL
Code: TR600
8.2.2 Other Protective Equipment:
9. TYPICAL PHYSICAL PROPERTIES:
- State : liquefied gas
- Color : incolor
- Odor Characteristics : Inodor
- Molecular weight : 58.1
- Solubility in Water : 0.03 g/100ml a 25°C a 1013 hPa
- Melting point : -159.6 °C a 1 bar
- Boiling Point : -11.7 °C a 1 bar
- Flash point : -82 °C a 1 bar
- Auto-ignition temperature : 477 °C
- Relative density : 2.01 Air=1
- Critical temperature : 135 °C
- Flammability limit : low 1.80-high 8.44 In air at 1 bar (% vol)
10. STABILITY AND REACTIVITY:
10.1 Chemical Stability:
Stable under normal conditions.
10.2 Hazardous Decomposition products:
These products carbon oxides (CO, CO2).
10.3 Incompatibility:
May react violently with oxidants. Can form explosive mixture with air.
10.4 Conditions to Avoid:
In a fire or if heated, a pressure increase will occur and the container may burst. Pressurised container: protect from sunlight and do not expose to
temperature exceeding 50°C. Do not pierce or burn, even after use.
11. TOXICOLOGICAL INFORMATION
Effects:
No known toxicological effects from this product.
Cancinogenic Effects:
These effects are not identified.
For more information on hazardous components, see sections 2 and 8.
Material Safety Data Sheet according to directive (UE) 453/2010 Page 5 of 6
R600a < 1000 mL
Code: TR600
12. ECOLOGICAL INFORMATION
Persistence and Degradation:
- ODP : 0
No known ecological damage caused by this product.
13. DISPOSAL INFORMATION
Do not discharge into areas where there is a risk of forming an explosive mixture with air. Waste gas should be flared through a suitable burner with flash
back arrestor. Do not discharge into any place where its accumulation could be dangerous. Contact supplier if guidance is required.
Procedure: Disposal of aerosol containers must be in accordance with local and national regulations.
14. TRANSPORT INFORMATION
14.1 Transport on road, Regular 94/55/CE (ADR 2013):
Class: 2 Shipping Isobutane Hazard Class 2.1 N. UN 1950 Aerosol
description
Code of classification: 5
Documents of transport: Documents of transport
14.2 Transport via sea (IMDG 32-04):
Class: Shipping Isobutane Hazard 2.1 N. UN 1950 Aerosol
description Class
Documents of transport: Documents of boarding.
14.3 Air freight (ICAO/IATA):
Classe: Shipping Isobutane Hazard Class 2.1 N. UN 1950 Aerosol
description
Documents of transport: Documents of aerial boarding.
15. REGULATORY INFORMATION
Reg. CE 1272/2008:
H220 – Extremely flammable.
H280 – Pressurised container; the container may burst with high temperature.
P210 – Keep away from sources of ignition - No smoking.
P377 - Take precautionary measures against static discharges.
P381 – Eliminare ogni fonte di accensione se non c'è pericolo.
P403 – Keep container in a well-ventilated place;
Material Safety Data Sheet according to directive (UE) 453/2010 Page 6 of 6
R600a < 1000 mL
Code: TR600
16. OTHER INFORMATION
Text of R phrases mentioned in section 2:
Extremely flammable.
Sure to read the safety information of Mariel. For more information contact the office or authorized distributors of Mariel.
Legislations on MSDS:
Safety Data Sheet agrees with the REACH directive.
Version 3:
Date of revision:
10/02/2014
All information, recommendations, and suggestions made by Mariel srl. (“Company”) appearing herein concerning our product are based upon tests and
data believed to be reliable. However, because of the variable characteristics of analytical procedures and samples, and the inability to control its
customers’ uses of…
